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Synlett 1997; 1997(8): 941-943
DOI: 10.1055/s-1997-927
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Regio and Stereoselective Synthesis of (E)-4-Arylidene/alkenylidene-3-tosyloxazolidin-2-ones through Palladium-Catalyzed Reactions of Aryl Iodides/Vinyl Triflates with Propargyl Tosylcarbamates

Antonio Arcadi*
  • *Dipartimento di Chimica Ingegneria Chimica e Materiali della Facoltà di Scienze, Università de L’Aquila, Via Vetoio, Coppito Due, I-67100 L’Aquila, Italy, Fax: 0039-862-433753; E-mail: arcadi@axscaq.aquila.infn.it
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Publication Date:
31 December 2000 (online)

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The palladium-catalyzed reaction of aryl iodides/vinyl triflates with propargyl tosylcarbamates produces regio and stereoselectively (E)-4-Arylidene/alkenylidene-3-tosyloxazolidin-2-ones in moderate to good yields.

palladium catalysis - tosylcarbamates - annulation - oxazolidinones