Download PDF
Synthesis 1997; 1997(12): 1391-1393
DOI: 10.1055/s-1997-1364
short paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Synthesis of 1,2,3,6-Tetrahydrophosphorin 1-Oxides by Regioselective Reduction

Györg Keglevich1 , Zsolt Böcskei2 , Kálmán Újszászy3 , László Tőke4
  • 1Department of Organic Chemical Technology, Technical University of Budapest, 1521 Budapest, Hungary, Fax +36(1)4633648; E-mail: keglevich@oct.bme.hu
  • 2Chinoin Pharmaceuticals, 1325 Budapest, Hungary
  • 3Department of General and Inorganic Chemistry, Loránd Eötvös University, 1518 Budapest, Hungary
  • 4Department of Organic Chemical Technology, Technical University of Budapest, 1521 Budapest, Hungary
Further Information

Publication History

Publication Date:
31 December 2000 (online)

 PDF Download  Permissions and Reprints All articles of this category

The title compounds 2a-e have been synthesized by the partial saturation of the hetero ring of 1,2-dihydrophosphorin 1-oxides 1a-e. The reduction was accomplished through regioselective hydroboration.

1,2-dihydrophosphorin - regioselective reduction - hydroboration - 1,2,3,6-tetrahydrophosphorin - stereostructure