RSS-Feed abonnieren
Bitte kopieren Sie die angezeigte URL und fügen sie dann in Ihren RSS-Reader ein.
https://www.thieme-connect.de/rss/thieme/de/10.1055-s-00000084.xml
Synthesis 1997; 1997(5): 509-511
DOI: 10.1055/s-1997-1228
DOI: 10.1055/s-1997-1228
short paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved.
This journal, including all individual contributions and illustrations published therein,
is legally protected by copyright for the duration of the copyright period. Any use,
exploitation or commercialization outside the narrow limits set by copyright legislation,
without the publisher's consent, is illegal and liable to criminal prosecution. This
applies in particular to photostat reproduction, copying, cyclostyling, mimeographing
or duplication of any kind, translating, preparation of microfilms, and electronic
data processing and storage.An Enantiocontrolled Synthesis of Both Enantiomers of Frontalin
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)

Both (+)- and (-)-enantiomers of frontalin, the aggregation pheromone of the Dendroctonus pine beetles, have been synthesized in an enantiocontrolled way from 2-acetyl-5-methylfuran by use of the Sharpless asymmetric dihydroxylation and the oxidative ring-expansion reactions as key steps.
frontalin - insect pheromone - asymmetric dihydroxylation - oxidative furan-ring expansion - chiral 6,8-dioxabicyclo[3.2.1]octance ring system