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Synthesis 1997; 1997(2): 171-172
DOI: 10.1055/s-1997-1157
short paper
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Regioselectivity of Deprotonation of Indoline and Tetrahydroquinoline Dithiocarbamic and Carbamic Compounds: A Correction

Hubertus Ahlbrecht1 , Dieter Kornetzky2 , Thomas Purder2 , Alan R. Katritzky3 , Ion Ghiviriga4 , Julian Levell4
  • 1Fachbereich Chemie der Universität Gießen, Institut für Organische Chemie, Heinrich-Buff-Ring 58, D-35392 Gießen, Germany, Fax +49(641)9934309; E-mail Hubertus.Ahlbrecht@chemie.uni-giessen.de
  • 2Fachbereich Chemie der Universität Gießen, Institut für Organische Chemie, Heinrich-Buff-Ring 58, D-35392 Gießen, Germany
  • 3Florida Center For Heterocyclic Compounds, University of Florida, Department of Chemistry, P.O. Box 117200, Gainesville, FL 32611-7200, USA, Fax +1(352)3929199; E-mail katritzky@chem.UFl.edu
  • 4Florida Center For Heterocyclic Compounds, University of Florida, Department of Chemistry, P.O. Box 117200, Gainesville, FL 32611-7200, USA
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Publikationsdatum:
31. Dezember 2000 (online)

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Deprotonation of indoline and tetrahydroquinoline dithiocarbamic and carbamic compounds takes place at the benzylic position and not at the α-carbon to nitrogen as previously reported.

Selective deprotonation of protected amines occurs in the benzyclic position