PDF herunterladen
Synlett 1997; 1997(12): 1467-1468
DOI: 10.1055/s-1997-1044
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Approach to Carbocyclic 4-Deoxypyrazofurin through Asymmetrisation of a meso-Norbornene Derivative

Barbara Mohar, JoŽe Kobe1 , Gerrit-Jan Koomen2
  • 1National Institute of Chemistry, Hajdrihova 19, 1115 Ljubljana, Slovenia, Fax 386 61 1259 244; joze.kobe@ki.si
  • 2University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The Netherlands, Fax 31 20 5255670; gjk@org.chem.uva.nl
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
31. Dezember 2000 (online)

 als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik
Preview

The first enantioselective synthesis of carbocyclic 4-deoxypyrazofurin 1a has been accomplished via (+)-4 which was prepared by asymmetric hydroboration or hydrosilylation reactions.

asymmetric hydrosilylation - asymmetric hydroboration - norbornanes - carbocyclic 4-deoxypyrazofurin