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Synlett 1997; 1997(11): 1300-1302
DOI: 10.1055/s-1997-1033
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The Synthesis of the Common C31-C40 Fragment of Pectenotoxins

Seiji Amano, Kenshu Fujiwara, Akio Murai*
  • *Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo 060, Japan
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Publication History

Publication Date:
31 December 2000 (online)

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The enantiomeric compound (2) corresponding to the common C31-C40 fragment of pectenotoxins, diarrhetic shellfish toxins, was first synthesized through the pathway involving the stereoselective generation of the α-lithiated tetrahydrofuran derivative (4) as the key stage.

pectenotoxin-1 - reductive lithiation - α-tetrahydrofuranyl lithium

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