PDF herunterladen
Synlett 1996; 1996(12): 1189-1190
DOI: 10.1055/s-1996-5703
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Convenient Asymmetric Synthesis of (1R,3R)-(+)- and (1S,3S)-(-)-1,3-Diphenylpropane-1,3-diols

Gregory H. P. Roos* , A. Richard Donovan
  • *Chemistry Department, Murdoch University, Murdoch 6150, Western Australia, Fax +61(9)3101711, e-mail roos@chem.murdoch.edu.au
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
31. Dezember 2000 (online)

 als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik
Preview

Kinetic resolution via a Sharpless epoxidation serves as the key step to provide the useful C2 chiral auxiliaries (R,R)- and (S,S)-1,3-diphenylpropane-1,3-diols, in good yield and high enantiomeric purity from the commercially available 1,3-diphenylprop-1-en-3-one.

Sharpless epoxidation - Kinetic resolution - Asymmetric synthesis - C2 symmetric 1,3-diols - 1,3-Diphenylpropan-1,3-diols