Download PDF
Synlett 1996; 1996(10): 975-977
DOI: 10.1055/s-1996-5637
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Stereoselective Synthesis of Unsaturated Polyhydroxylated Amino Acids via Ester Enolate Claisen Rearrangement

Uli Kazmaier* , Christiane Schneider
  • *Organisch-Chemisches Institut der Universität, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, Fax: +49(6221)544205
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

Ester enolate Claisen rearrangement of chelated N-protected chiral allylic amino acid esters results in the formation of polyhydroxylated γ,δ-unsaturated amino acids in good yields and with a high degree of chirality transfer.

Chelated enolate - Claisen rearrangement - polyhydroxylated amino acids - α-alkylated amino acids

      >