A Novel Reduction of Zinc(II) Chloride with Samarium Metal and its Application to Silylation of 1-Alkynes

Hikaru Sugita; Yasuo Hatanaka; Tamejiro Hiyama

doi:10.1055/s-1996-5582

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Synlett 1996; 1996(7): 637-639
DOI: 10.1055/s-1996-5582

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A Novel Reduction of Zinc(II) Chloride with Samarium Metal and its Application to Silylation of 1-Alkynes

Hikaru Sugita^* , Yasuo Hatanaka, Tamejiro Hiyama

^*Sagami Chemical Research Center, 4-4-1 Nishiohnuma, Sagamihara, Kanagawa 229, Japan, Fax: 0427-49-7631

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Publication Date:
31 December 2000 (online)

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Samarium metal-induced reduction of zinc(II) chloride provides a convenient and efficient route to activated zinc, which allows us to silylate 1-alkynes with chlorosilanes effectively.

Samarium - Zinc Chloride - Activated Zinc - Silylation - Alkynylsilane