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Synlett 1996; 1996(6): 529-530
DOI: 10.1055/s-1996-5499
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The 5 or 6 HF-Et3N Complex, Mild and Selective Hydrofluorination Agents for tert-Alkyl Fluorides

Shoji Hara* , Mikio Kameoka, Norihiko Yoneda1
  • *Division of Molecular Chemistry, Graduate School of Engineering, Hokkaido University, Sapporo 060, Japan
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Publication History

Publication Date:
31 December 2000 (online)

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5 or 6 HF-Et3N reacted with a variety of branched alkenes to give the tertiary alkyl fluorides selectively. They reacted with dienes at the more reactive double bond selectively and they have no influence on the functional groups such as the ketone or alcohol moiety in the molecules.

HF-Et3N complex - hydrofluorination reaction

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