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Synthesis 1996; 1996(3): 403-406
DOI: 10.1055/s-1996-4214
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A Simple Route to 3-Substituted 2-Cyano Allylic Alcohols

Mouna Aiai, Michèle Baudy-Floc’h, Albert Robert, Philippe Le Grel*
  • *Laboratoire de Chimie Structurale, URA CNRS 704, Université de Rennes I, Campus de Beaulieu, F-35042 Rennes Cédex, France, Fax +33(99)286739
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Publikationsdatum:
31. Dezember 2000 (online)

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The first original and simple route to 3-substituted 2-cyano allylic alcohols with very good yields is described. The epoxide function in the key step acts as a protecting group during the synthesis of these allylic alcohols.

2-cyano allylic alcohols - bromohydrins - stereoselective ring opening - reduction - epoxide function as protecting group