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Synlett 1995; 1995(10): 1035-1036
DOI: 10.1055/s-1995-5183
DOI: 10.1055/s-1995-5183
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Stereoselective Synthesis of γ,δ-Unsaturated α-Hydroxyphosphonates through [2,3]-Wittig Sigmatropic Rearrangement of α-Allyloxyphosphonates
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Publication History
Publication Date:
31 December 2000 (online)
The [2,3]-Wittig sigmatropic rearrangement of α-allyloxyphosphonate is shown to give γ,δ-unsaturated α-hydroxyphosphonate with high degree of stereoselectivity.
α-allyloxyphosphonates - γ,δ-unsaturated α-hydroxyphosphonates - [2,3]-Wittig sigmatropic rearrangement - diastereoselection