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Synlett 1995; 1995(10): 1040-1042
DOI: 10.1055/s-1995-5181
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Atropisomerization of Biaryl Cr(CO)3 Complexes: Preparation of Both Atropisomers of Biaryls

Ken Kamikawa, Takashi Watanabe, Motokazu Uemura*
  • *Faculty of Science, Osaka City University, Sugimoto 3-3-138, Sumiyoshi-ku, Osaka 558, Japan
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Publication Date:
31 December 2000 (online)

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Both enantiomerically pure biaryls with an axial chirality can be prepared from a single planarly chiral (arene)Cr(CO)3 complex by Suzuki-Miyaura cross-coupling and subsequent axial isomerization.

chiral biaryl - axial chirality - planar chirality - axial isomerization - (arene)chromium complex