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Synlett 1995; 1995(6): 666-668
DOI: 10.1055/s-1995-5019
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Chemoselective oxidation of [(arylthioalkyl pyrrolidino)carbenechromium(0) pentacarbonyl complexes: synthesis of (arylsulfinyl and arylsulfonylalkyl pyrrolidino)carbene complexes

Clara Baldoli, Paola Del Buttero, Emanuela Licandro, Stefano Maiorana* , Antonio Papagni1
  • *Dipartimento di Chimica Organica e Industriale, Università di Milano, via Golgi 19, I-20133 Milano, Italy
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Publication Date:
31 December 2000 (online)

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The chemoselective oxidation of pentacarbonyl-[amino(arylthioalkyl)carbene]chromium(0) complexes by using N-sulfonyloxaziridine or dimethyldioxirane affords the corresponding sulfoxide or sulfone derivatives in good to high chemical yields.

Fischer carbene complexes - chemoselective oxidation