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Synlett 1995; 1995(4): 349-350
DOI: 10.1055/s-1995-4978
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Regioselective Phenylselenenylation at the 5-Position of Pyrimidine Nucleosides Mediated by Manganese(III) Acetate

Dong Hoon Lee, Yong Hae Kim*
  • *Department of Chemistry, Korea Advanced Institute of Science and Technology, Kusong-dong, Yusong-gu, Taejon, 305-701, Korea
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Publication Date:
31 December 2000 (online)

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5-(Phenylseleno)pyrimidine nucleosides are obtained in high yields by the reaction of pyrimidine nucleosides with manganese (III) acetate and diphenyl diselenide in acetic acid. A selenium electrophile generated by the reaction of manganese(III) acetate with diphenyl diselenide appears to take an important role.

Nucleoside - Phenylselenenylation - Manganese Acetate

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