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Synlett 1995; 1995(2): 163-164
DOI: 10.1055/s-1995-4906
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Trialkylsilyl Triflate Promoted Conjugate Addition of Organoaluminates to α,β-Unsaturated Ketones

Sunggak Kim* , Joo Hyeon Park
  • *Department of Chemistry, Korea Advanced Institute of Science and Technology, Taejon 305-701, Korea
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Publication History

Publication Date:
31 December 2000 (online)

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Trialkylsilyl triflate promotes the conjugate addition of alkenyl and alkynyl groups of organoaluminates to α,β-unsaturated ketones to afford β-alkylated silyl enol ethers in high yields.

Organoaluminates - alkenylation - alkynylation - trialkylsilyl triflate - conjugate addition - α,β-enones