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Synlett 1995; 1995(1): 116-118
DOI: 10.1055/s-1995-4867
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1,2-Stereoinduction in β-Oxy-Radicals: The Influence of the α-Substituent

Bernd Giese* , Michel Bulliard, Joachim Dickhaut, Ralf Halbach, Carla Hassler, Ursula Hoffmann, Berthold Hinzen, Martin Senn
  • *Department of Chemistry, University of Basel, St. Johanns Ring 19, CH-4056 Basel, Switzerland
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Publication Date:
31 December 2000 (online)

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1,2-Stereoinduction is studied in H-abstraction reactions of acyclic radicals with a methyl and a tert-butyldiphenylsiloxy group at the stereogenic center. The extent of the stereoselectivity depends significantly upon the substituent at the radical center.

1,2-stereoinduction - β-oxy-radicals - A-strain - Felkin-Anh rule