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Synlett 1995; 1995(1): 121-122
DOI: 10.1055/s-1995-4856
DOI: 10.1055/s-1995-4856
letter
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”Three Components” Synthesis of Vinyl Cyclopropane Carboxylic Acids
Further Information
Publication History
Publication Date:
31 December 2000 (online)
γ-Hydroxyalkyl allyl stannanes and -silanes lead selectively to a large variety of products depending upon the reagent used (BF3.OEt2 or thionyl chloride). Suitable combination allows the synthesis of vinyl cyclopropane carboxylic acids including chrysanthemic acid, the constituent of the most potent commercially available pyrethroid insecticide.
chrysanthemic acid - allyl stannanes - allyl silanes - γ-hydroxyalkyl stannanes