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Synthesis 1995; 1995(3): 325-329
DOI: 10.1055/s-1995-3895
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Neue Organometall-Derivate des 1,6-Methanol[10]annulens

Richard Neidlein* , Stephan Gürtler
  • *Pharmazeutisch-chemisches Institut der Universität Heidelberg, Im Neuenheimer Feld 364, D-69120 Heidelberg, Deutschland
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Publikationsdatum:
31. Dezember 2000 (online)

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Fischer-type amine-carbene complexes of 1,6-methano[16]annulenes 4a-e were prepared in high yields by the aminolyses of 1,6-methano[10]annulenyl substituted alkoxy-carbene complexes 1 with various amines 2a-e. The benzylamino complex 4c was selectively transformed into the benzylamide 5 by oxidation or to the acylamino chelate carbene complex 6 by acylation catalyzed by dimethylaminopyridine.

1,6-methano[10]annulen - amino-Fischer-carben-komplexe - acylamino-chelat-komplex - oxidation

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