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Synthesis 1994; 1994(9): 913-914
DOI: 10.1055/s-1994-25601
short paper
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Studies on Macrocyclic Diterpenoids; Part 13: An Efficient Total Synthesis of (±)-Sarcophytol-M

Yulin Li* , Xiangjun Yue
  • *State Key Laboratory of Applied Organic Chemistry and Institute of Organic Chemistry, Lanzhou University, Lanzhou 730000, People's Republic of China
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Publikationsdatum:
17. September 2002 (online)

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The total synthesis of (±)-sarcophytol-M, a marine cembranol, was achieved from (E)-geraniol in twelve steps by using an intramolecular nucleophilic addition of a sulfur-stabilized carbanion to a ketone as the key step.