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Synthesis 1994; 1994(7): 685-686
DOI: 10.1055/s-1994-25546
short paper
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An Improved Synthesis of Conjugated Nitroolefins

Anil K. Saikia* , Nabin C. Barua, R. P. Sharma, Anil C. Ghosh
  • *Natural Products Chemistry Group, Organic Chemistry Division, Regional Research Laboratory, Jorhat 785006, Assam, India
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Publication History

Publication Date:
17 September 2002 (online)

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ß-Nitro alcohols 1 react with triphenylphosphine/carbon tetrachloride/triethylamine under reflux to give the corresponding nitroolefins 2 in good yields (80-95%). Other groups such as tertiary hydroxyl, ether, halide etc. remain unaffected, and the nitroolefins so produced are exclusively the (E)-isomers.

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