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Synlett 1994; 1994(11): 902-904
DOI: 10.1055/s-1994-23042
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A New Approach to Carbacyclin by Using Claisen Rearrangement of Cyclic Orthoester

Takashi Takahashi* , Masahiro Miyazawa, Yasuharu Sakamoto, Haruo Yamada
  • *Department of Chemical Engineering, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152, JAPAN
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Publication Date:
22 March 2002 (online)

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New synthetic approach to a chiral carbacyclin by using Claisen rearrangement of cyclic orthoester and its diastereoselectivity based on MM2 transition state model are described.