Bismuth (III) Chloride - Catalyzed Chlorination of Alcohols by Chlorosilanes1

Mireille Labrouillère; Christophe Le Roux; Hafida Gaspard-Iloughmane; Jacques Dubac

doi:10.1055/s-1994-22985

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Synlett 1994; 1994(9): 723-724
DOI: 10.1055/s-1994-22985

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Bismuth (III) Chloride - Catalyzed Chlorination of Alcohols by Chlorosilanes¹

Mireille Labrouillère^* , Christophe Le Roux, Hafida Gaspard-Iloughmane, Jacques Dubac

^*Laboratoire des Organométalliques (URA-CNRS 477), Université Paul-Sabatier, 118 route de Narbonne, 31062 Toulouse (France)

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Publication Date:
18 September 2002 (online)

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In the presence of catalytic amounts of BiCl₃, chloromethylsilanes could be used as chlorinating agents of alcohols and alkoxysilanes. At rt , t-butanolysis of polychlorosilanes led to polysiloxanes in quantitative yield.

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