A Convenient, Short Synthesis of (E)-1,3-Butadienyl(tributyl)stannane

Ana M. Gómez; J. Cristóbal López; Bert Fraser-Reid

doi:10.1055/s-1993-25971

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Synthesis 1993; 1993(10): 943-944
DOI: 10.1055/s-1993-25971

short paper

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A Convenient, Short Synthesis of (E)-1,3-Butadienyl(tributyl)stannane

Ana M. Gómez^* , J. Cristóbal López, Bert Fraser-Reid

^*Paul M. Gross Chemical Laboratory, Department of Chemistry, Duke University, Durham, North Carolina, 27706, USA

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Publication Date:
29 April 2002 (online)

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A ready two-step procedure for medium scale preparation of (E)-1, 3-butadienyl(tributyl)stannane involves stannylation (Bu₃SnI-lithium hexamethyldisilazide) of 2,5-dihydrothiophene S,S-dioxide (3-sulfolene) followed by thermal extrusion of sulfur dioxide.

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