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Synlett 1992; 1992(12): 965-966
DOI: 10.1055/s-1992-21546
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Convenient Synthesis of Monoselenoacetals from Acetals with Phenyl Trimethylsilyl Selenide

Makoto Sakakibara* , Kazuhiro Katsumata, Yoshihiko Watanabe, Takeshi Toru, Yoshio Ueno
  • *Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466, Japan
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Publication Date:
08 March 2002 (online)

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Monoselenoacetals can be efficiently prepared from acetals by treatment with phenyl trimethylsilyl selenide in the presence of a catalytic amount of trimethylsilyl trifluoromethanesulfonate. This procedure also effects the transformation of acetyl glucoside into selenoglucoside.