Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000083.xml
Synlett 1992; 1992(11): 897-900
DOI: 10.1055/s-1992-21533
DOI: 10.1055/s-1992-21533
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved.
This journal, including all individual contributions and illustrations published
therein, is legally protected by copyright for the duration of the copyright period.
Any use, exploitation or commercialization outside the narrow limits set by copyright
legislation, without the publisher's consent, is illegal and liable to criminal prosecution.
This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing
or duplication of any kind, translating, preparation of microfilms, and electronic
data processing and storage.Enantioselective Synthesis of 3-Oxoesters and Carboxylic Acids as Polyfunctional Small Building Blocks with a Quaternary Stereogenic Center
Further Information
Publication History
Publication Date:
08 March 2002 (online)

Polyfunctional 2-substituted 3-oxoesters 4 and carboxylic acids 6 bearing a quaternary stereogenic center are synthesized in good overall yields and high enantiomeric excesses via SAMP/-RAMP-hydrazones. The absolute configuration is confirmed by X-ray structure analysis of 3-oxoester 4i and carboxylic acid 6a.