Download PDF
Synlett 1992; 1992(11): 883-886
DOI: 10.1055/s-1992-21527
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Ethylenic Acylsilanes as Synthetic Equivalents of Sila β-Acyl Anions

Alessandro Degl'Innocenti* , Paola Ulivi, Antonella Capperucci, Gianna Reginato, Alessandro Mordini, Alfredo Ricci
  • *Centro C.N.R. sulla Chimica e la Struttura dei Composti Eterociclici e loro Applicazioni, via G. Capponi, 9, I-50121 Firenze, Italy
Further Information

Publication History

Publication Date:
08 March 2002 (online)

 PDF Download  Permissions and Reprints All articles of this category

Ethylenic trimethylsilyl ketone 1 affords, upon treatment with PhSSiMe3 in the presence of BF3.Et2O, 1-trimethylsilyl-1, 3-bis(phenylthio)propene which has been shown to act as a useful sila β-acyl vinyl anion equivalent, opening a novel access to richly functionalized α,β-unsaturated acylsilanes.