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Synlett 1992; 1992(9): 751-752
DOI: 10.1055/s-1992-21481
DOI: 10.1055/s-1992-21481
letter
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Oxidation of 2-Aryl-1,2,3,4-tetrahydro-4-quinolones: A Novel Entry for the Synthesis of 2- and 3-Arylquinoline Alkaloids
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Publication History
Publication Date:
08 March 2002 (online)
Oxidation of 2-aryl-1,2,3,4-tetrahydro-4-quinolines 1a-d and their N-acetyl derivatives 3a-d using thallium(III) nitrate and thallium(III) p-tolylsulphonate in acetonitrile-trialkyl orthoformate provides a novel entry for the synthesis of 4-alkoxy-2-arylquinolines 2a-e and 3-aryl-4-quinolone alkaloids, respectively.