PDF herunterladen
Synlett 1992; 1992(7): 585-586
DOI: 10.1055/s-1992-21424
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Remote Asymmetric Induction in Reactions between Allylstannanes and Aldehydes: Influence of a Homoallyl Ether Substituent in the Stannane

John S. Carey* , Eric J. Thomas
  • *Department of Chemistry, University of Manchester, Manchester M13 9PL, England
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
08. März 2002 (online)

 als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik

Transmetallation of (4R)-4-methyl-5-phenylmethoxypent-2-enyl(tributyl)stannane (7) using tin(IV) chloride gives an intermediate which reacts with aldehydes with excellent 1,5-asymmetric induction. For example, benzaldehyde yielded (1S,3Z,5R)-5-methyl-1-phenyl-6-phenylmethoxy-3-hexenol (8) in 86% yield.