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Synthesis 1991; 1991(9): 787-788
DOI: 10.1055/s-1991-26575
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A Convenient and General Synthesis of Alkylcarbamates from Tertiary Isocyanates and Alcohols

A. Benalil* , P. Roby, B. Carboni, M. Vaultier
  • *Groupe de Recherche de Physicochimie Structurale, U.R.A. C.N.R.S. no 704, Université de Rennes I, Avenue du Général Leclerc, F-35042 Rennes Cédex, France
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Publication Date:
29 April 2002 (online)

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Reaction of primary, secondary and tertiary alkyl isocyanates with benzyl alcohol, tert-butyl alcohol or 1-adamantanol in the presence of 5% hydrogen chloride provides a mild and convenient method for alkyl alkylcarbamate synthesis.