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Synthesis 1991; 1991(8): 647-648
DOI: 10.1055/s-1991-26535
DOI: 10.1055/s-1991-26535
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved.
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or duplication of any kind, translating, preparation of microfilms, and electronic
data processing and storage.An Improved Synthesis of Perfluorocarboxylic Acids
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Publikationsdatum:
29. April 2002 (online)
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Perfluoroalkyl iodides CnF2n+1CF2I (3 < n < 7) were converted to perfluoroalkanecarboxylic acids CnF2n+1CF2CO2H in 91% yield, by reaction with zinc-copper couple in the presence of solid carbon dioxide in trimethyl phosphate as the solvent.