Synthesis 1991; 1991(4): 273-274
DOI: 10.1055/s-1991-26443
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2-Amino-2-deoxyglycoside Derivatives via Hofmann Rearrangement of 2-Carbamoyl-2-deoxyglycosides

Danuta Mostowicz* , Czesław Bełżecki, Marek Chmielewski
  • *Institute of Organic Chemistry, Polish Academy of Sciences, P-01-224 Warsaw, Poland
Further Information

Publication History

Publication Date:
29 April 2002 (online)

Methyl 2-methoxy- and 2-tert-butoxycarbonylamino-2-deoxyglycosides were obtained from methyl 2-carbamoyl-2-deoxyglycosides via Hofmann rearrangement with sodium methoxide/bromine/methanol or sodium hydroxide/sodium bromite/methanol or lead tetraacetate tert-butyl alcohol/dimethylformamide.