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Synthesis 1991; 1991(4): 267-269
DOI: 10.1055/s-1991-26441
DOI: 10.1055/s-1991-26441
paper
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[3 + n] Annulation Reactions by Means of 3-Trimethylstannyl-2-[(trimethylstannyl)methyl]propene, an Isobutene Dianion Synthetic Equivalent
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Publication Date:
29 April 2002 (online)
Stepwise functionalization of the two carbon-tin bonds in 3-trimethylstannyl-2-[(trimethylstannyl)methyl]propene with electrophiles (diacyl dichlorides or aldehydes and carbon dioxide, provides a promising route for [3 + n] annulation reactions.