Download PDF
Synlett 1991; 1991(7): 509-510
DOI: 10.1055/s-1991-20781
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Development of a New ß-Acylvinyl Anion Equivalent from 1-(Methylsulfinyl)alka-1,2-dienes

Jean-Bernard Baudin* , Sylvestre A. Julia, Robert Lorne
  • *Laboratoire de Chimie, Ecole Normale Supérieure, 24 rue Lhomond, F-75231 Paris Cedex 05, France
Further Information

Publication History

Publication Date:
07 March 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

By deprotonation with methyllithium or lithium diisopropylamide and reaction with alkyl halides, the allenic methyl sulfoxides 2 [1-(methylsulfinyl)alka-1,2-dienes] have been converted into substituted propargylic sulfoxides 5 [1,3-disubstituted 1-(methylsulfinyl)-2-alkynes]. Smooth desulfurization of 5 using 2-mercapto-1-methylimidazole furnished the corresponding conjugated enones 9.

      >