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Synlett 1991; 1991(7): 472-474
DOI: 10.1055/s-1991-20764
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A Model for the Synthesis of the Tigliane and Daphnane Diterpenes Using an Intramolecular Diels-Alder Reaction

Philip C. Bulman Page* , David C. Jennens, Roderick A. Porter, Alan N. Baldock
  • *Robert Robinson Laboratories, Department of Chemistry, University of Liverpool, P.O. Box 147, Liverpool L69 3BX, England
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Publication Date:
07 March 2002 (online)

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A synthesis of the tricyclo[9.3.0.02,7]tetradecane ring system of the daphnanes and tiglianes has been achieved in five steps from 2-cyclopenten-1-one using an unusual intramolecular Diels-Alder reaction as the cornerstone.

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