Synlett 1990; 1990(2): 113-114
DOI: 10.1055/s-1990-34713
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Regiospecific Synthesis of Vinylgermyl Compounds from Alkynes or Allenes and Free Singlet Dimethylgermylene

Gilbert Billeb* , Hartmut Brauer, Wilhelm P. Neumann
  • *Lehrstuhl für Organische Chemie I der Universität Dortmund, Otto-Hahn-Strasse 6, D-4600 Dortmund 50, Federal Republic of Germany
Further Information

Publication History

Publication Date:
08 March 2002 (online)

New 2- and 1,2-substituted vinylgermyl acylates, alkoxides, and halides are formed regioselectively in high yields from alkynes or allenes and free singlet dimethylgermylene in the presence of the protic reagents carboxylic acids, alcohols, or hydrohalic acids.

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