Preparation of Crowded Olefins. Alkylidenation of Polycycloalkanones by Corey Homologative Epoxidation Followed by Reaction with Lithium Dialkylcuprates and with Thionyl Chloride

George A. Olah; An-hsiang Wu

doi:10.1055/s-1990-27043

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Synthesis 1990; 1990(10): 887-889
DOI: 10.1055/s-1990-27043

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Preparation of Crowded Olefins. Alkylidenation of Polycycloalkanones by Corey Homologative Epoxidation Followed by Reaction with Lithium Dialkylcuprates and with Thionyl Chloride

George A. Olah^* , An-hsiang Wu

^*Donald P. and Katherine B. Loker Hydrocarbon Research Institute and the Department of Chemistry, University of Southern California, Los Angeles, CA 90089-1661, USA

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Publikationsdatum:
17. September 2002 (online)

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Preparation of crowded olefins from polycycloalkanones via Corey homologative epoxidation by trimethylsulfoxonium iodide/potassium tert-butoxide followed by reaction with lithium dialkylcuprates and thionyl chloride giving the corresponding alkylidenepolycycloalkanes is reported.