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Synthesis 1990; 1990(8): 654-656
DOI: 10.1055/s-1990-26970
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1,2,3-Triazolo[1,5-a]quinolines, -[1,7]naphthyridines, and -benzo[1,5]diazepines by the Action of Diethyl 1,3-Acetonedicarboxylate Anion on ortho-Substituted Aryl Azides

Robert K. Smalley* , Mabrouk Teguiche
  • *Department of Chemistry and Applied Chemistry, University of Salford, Salford, M5 4WT, England
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Publication Date:
17 September 2002 (online)

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The title compounds were prepared by the action of the diethyl 1,3-acetonedicarboxylate anion on ortho-substituted aryl azides. The anion was formed using either a sodium alkoxide in the appropriate alcohol or by an ion-exchange resin [Amberlite IRA-400(OH)].