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Synlett 1990; 1990(12): 737-738
DOI: 10.1055/s-1990-21231
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Azidocubanes; 2. Acid-Induced Rearrangement: Formation of 9-Azahomocubanes1

Philip E. Eaton* , Allison M. Fisher, Robert E. Hormann
  • *Department of Chemistry, The University of Chicago, Chicago, Illinois 60637, USA
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Publication Date:
08 March 2002 (online)

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Rearrangements in acid of cubyl azides, prepared from the corresponding amines using trifluoromethanesulfonyl azide in the presence of triethylamine, are shown to produce 1-substituted 9-azahomocubanes.

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