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Synlett 1990; 1990(10): 575-576
DOI: 10.1055/s-1990-21169
DOI: 10.1055/s-1990-21169
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Synthesis of (±)-Meroquinene and Its Epimer via an Allylic Radical Cyclization
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Publikationsverlauf
Publikationsdatum:
08. März 2002 (online)
±-Meroquinene (1; cis-3-ethenyl-4-piperideneacetic acid) and its trans epimer 2 were prepared via an allylic radical cyclization of ethyl (2EZ,8Z)-6-benzoyl-10-bromo-6-aza-2,8-decadienoate (15) in good yield.