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Synlett 1990; 1990(7): 415-416
DOI: 10.1055/s-1990-21111
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Synthesis of Phosphinic and Phosphonic Analogues and C-Arylglycines

Kamyar Afarinkia* , John I.G. Cadogan, Charles W. Rees
  • *Department of Chemistry, Imperial College of Science, Technology and Medicine, South Kensington, London SW7 2AY, England
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Publication Date:
08 March 2002 (online)

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The addition of trimethylsilyloxy phosphorus(III) derivatives, generated in situ, to N-benzylideneallylamines at room temperature followed by catalytic de-allylation provides a mild, high yielding route to α-aminobenzylphosphonates and α-aminobenzylphosphinates.

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