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Synlett 1990; 1990(5): 267-269
DOI: 10.1055/s-1990-21059
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Poly-4-vinylpyridinium Poly(hydrogen fluoride): A Convenient Polymeric Fluorinating Agent1

George A. Olah* , Xing-Ya Li
  • *Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, Los Angeles, CA 90089-1661, USA
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Publication History

Publication Date:
08 March 2002 (online)

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Poly-4-vinylpyridinium poly(hydrogen fluoride), PVPHF, a solid polymeric poly(hydrogen fluoride), was prepared and used as a fluorinating agent for hydrofluorination and bromofluorination of alkenes and alkynes and for the fluorination of alcohols.The advantages of this method are easy handling and extremely convenient work-up.