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Synlett 1990; 1990(5): 259-260
DOI: 10.1055/s-1990-21055
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Stereochemistry of Aluminum Chloride Catalyzed Hydrosilylation of Methylcyclohexenes

Keiji Yamamoto* , Makoto Takemae
  • *Department of Chemical Engineering, Tokyo Institute of Technology, Meguro, Tokyo 152, Japan
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Publication Date:
08 March 2002 (online)

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Novel aluminum chloride catalyzed hydrosilylation of 1-methylcyclohexene with dimethylchlorosilane proceeds regioselectively and in a trans manner to give cis-2-methyl-1-(dimethylchlorosilyl)cyclohexane, which is converted to cis-2-methylcyclohexanol for structure identification by the oxidative cleavage of the Si-C bond with retention of configuration.