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Synthesis 1989; 1989(4): 298-300
DOI: 10.1055/s-1989-27230
DOI: 10.1055/s-1989-27230
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Diastereofacial Selectivity in the Reaction of (C-1)-Metalated Alkyldiphenylphosphine Imides with Schiff Bases
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Publication History
Publication Date:
17 September 2002 (online)
erythro-2-Anilinoalkyldiphenyphosphine phenylimides are obtained by reaction of (C-1)-metalated alkyldiphenylphosphine imides with aldimines in a diastereoselective fashion. Reaction of the products with carbon dioxide or with lithium aluminum hydride leads to 2-anilinoalkyldiphenylphosphine oxides or 2-anilinoalkyldiphenylphosphines, respectively.