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Synthesis 1988; 1988(12): 962-963
DOI: 10.1055/s-1988-27766
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Synthesis of β,γ-Unsaturated Carboxylic Acid Esters via Aryloxycarbonylation of Allylsilanes

Herbert Mayr* , Anton Cambanis, Englbert Bäuml
  • *Institut für Chemie der Medizinischen Universität zu Lübeck, Ratzeburger Allee 160, D-2400 Lübeck 1, Federal Republic of Germany
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Publication Date:
20 August 2002 (online)

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The β,γ-unsaturated carboxylic acid 4-chlorophenyl esters 3a-e are synthesized from the allylsilanes 2a-e and dichlorobis(4-chlorophenoxy)methane (1) in the presence of 1.1 equivalents of tin(IV) chloride.

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