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Synthesis 1988; 1988(8): 616-619
DOI: 10.1055/s-1988-27654
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Synthesis of 1,1-Bis(seleno)-2-alkenes

R. Dieden* , L. Hevesi
  • *Department of Chemistry, Facultés Universitaires Notre-Dame de la Paix, 61, rue de Bruxelles, B-5000 Namur, Belgium
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Publication Date:
20 August 2002 (online)

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The success of the direct conversion of α,β-unsaturated carbonyl compounds into the corresponding diselenoacetals by means of selenol/zinc chloride or tris(seleno)borane greatly depends on the starting carbonyl derivative. Enals and cyclic enones are transformed most efficiently, whereas acyclic enones mainly produce 1,4-addition compounds.

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