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Synthesis 1988; 1988(7): 562-564
DOI: 10.1055/s-1988-27641
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Functionalized Phosphine Imides. Diastereoselective Synthesis of β-Hydroxyphosphorylated Derivatives

José Barluenga* , Fernando López, Francisco Palacios
  • *Departamento de Química Organometálica, Facultad de Química, Universidad de Oviedo, E-33071 Oviedo, Spain
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Publication Date:
18 September 2002 (online)

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The diastereoselective synthesis, of 2-hydroxyalkyldiphenylphosphine phenylimides 2 and oxides 3 by reaction of α-metallated phosphine imides with aldehydes is described. When dimethylformamide or dimethyl disulfide were used as electrophiles, functionalized phosphine imides 4 or 6 were obtained, respectively.