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Synthesis 1988; 1988(7): 541-544
DOI: 10.1055/s-1988-27631
DOI: 10.1055/s-1988-27631
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A Highly Regio- and Chemoselective Ring Opening of Epoxides with Trimethylsilyl Azide/Aluminum Isopropoxide
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Publication History
Publication Date:
18 September 2002 (online)
Functionalized epoxides are regioselectively opened using trimethylsilyl azide/aluminum isopropoxide giving 2-trimethylsiloxy azides by attack on the less substituted carbon.