Synthesis 1988; 1988(6): 449-452
DOI: 10.1055/s-1988-27603
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Synthese von 5-Ring-Heterocyclen aus Maleinimiden

Karl-Heinz Etzbach* , Heinz Eilingsfeld
  • *Farbenlaboratorium der BASF AG, D-6700 Ludwigshafen, Federal Republic of Germany
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Publikationsdatum:
20. August 2002 (online)

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Synthesis of Five-Membered Heterocyles from Maleimides New heterocycles containing maleimide building blocks were prepared via 2-chloro-3-cyanomaleimide or 2,3-dichloromaleimides as key intermediates. Of the heterocyclic amines thus prepared, the following systems are useful as diazo components for preparing disperse dyes: 5-aminopyrazole-3,4-dicarboximides 5, 4-amino-5-alkoxycarbonylthiophene-2,3-dicarboximides 7, 5-aminoisothiazole-3,4-dicarboximides 9, 5-aminoisothiazole-3,4-dicarboxamide (10), 5-amino-3,4-dicyanoisothiazole (12), 5-amino-4-cyanothiophene-2,3-dicarboximides 15, and 2-aminothiazole-4, 5-dicarboximides 17.