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Synthesis 1988; 1988(4): 328-329
DOI: 10.1055/s-1988-27559
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Deprotection of Tetrahydropyranyl and Silyl Ethers Catalyzed by Organotin Phosphate Condensates

Junzo Otera* , Yoshihisa Niibo, Sadamasa Chikada, Hitosi Nozaki
  • *Department of Applied Chemistry, Okayama University of Science, Ridai-cho, Okayama 700, Japan
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Publikationsdatum:
20. August 2002 (online)

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A new method for deprotecting tetrahydropyranyl and silyl ethers has been established by using organotin phosphate condensates as a catalyst. The reaction proceeds selectively under mild conditions. The heterogenous reaction enables easy separation of the catalyst, which can be reused for further reactions without purification.